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HPLC method for polysulphides

Discussions about HPLC, CE, TLC, SFC, and other "liquid phase" separation techniques.

2 posts Page 1 of 1
Hello,

I need to develop an HPLC method for sodium polysulfides Na2Sx, with x ranging from 1 to 12.

The sample is dissolved in ethanol.

My initial thought was to try an ion pair method with a pH as high as the column can tolerate (to avoid loss of the lower hydrogen sulfides)

Detection should be possible in the lower UV.

What is the opinion of the community?


Etienne Jooken

I'm not an expert in the field, but may be you will find those references usefull


http://www.hamiltoncomp.com/cgi-shl/pro ... pplist2463
http://www.sdk.co.jp/shodex/english/dc070256.htm
2 posts Page 1 of 1

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