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GC of Cyanouryl Chloride

Posted: Wed Dec 24, 2008 3:47 pm
by Chandresh K. Soni
Someone help me .
i am working with Cyanouryl Chloride (C3Cl3N3) and tried the GC analysis on TC-5 Column. i got the response in Ethyl acetate but when i prepaired the solutin in MeOH it will give three peaks.

cyanourylchloride

Posted: Wed Dec 24, 2008 6:01 pm
by praveenpaliwal
2,4,6-trichloro-1,3,5-triazinetriium,2,4,6-trichloro-1,3,5-triazine-1,3-diium,
2,4,6-trichloro-1,3,5-triazin-1-ium , three possibilities are make and converts ur compounds in three peaks .

Because methanol has Proton doneting tendencies and Nitrogen is neighbour of -Cl atoms But more posssibility is that the lone pair of eletrone of Nitrogen does'nt take part in ring conjugation so that it can easily accept the proton and basic structure of compund is change. So that u find three peaks .[/img][/list][/quote][/code]