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revers phase system for hidrocortisone base

Posted: Wed Jul 02, 2008 8:45 am
by paul duque
dear collegues

i m looking for a reverse phase chromatographic system to separate hidrocortisone and prednisolone (resolution solution).

I tried with a L3 column and i used water and THF (70:30) in my mobile phase.
I used a L1 column too. Methanol and CH3CN dont work.
The molecules both,show the same retention time...
I use a UV detection at 254 nm-
Many thanks for your comments

Best Regards
Paul

Posted: Wed Jul 02, 2008 3:08 pm
by Bryan Evans
Below is an application for prednisilone and hydrocortisone separated on Cadenza CD-C18 (L1):
http://www.silvertonesciences.com/files/TI119E.pdf

Posted: Thu Jul 03, 2008 1:30 pm
by ym3142
paul, can you let us know the details?