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SRI8610 GC for CO2 Detection, using mole sieve column

Posted: Thu Jun 28, 2007 9:06 pm
by gadhamvr
Hello All.

I am currently using SRI 8610 GC for H2 Detection, using

Mole sieve 5A 80/100
Argon as Carrier gas
Oven Temp- 70 C
Injection volume - 0.5 mL

Can I still detect CO2, with the same column, while still detecting hydrogen gas.

Please Suggest!!!

Ramana

Posted: Fri Jun 29, 2007 12:29 pm
by chromatographer1
No, not possible. Replace the ms5A with ms13x or preferably a 3m porous polymer column.

best wishes,

Rod

MS5A with MS13x

Posted: Fri Jun 29, 2007 3:02 pm
by gadhamvr
Rod,

If I replace MS5A with MS13x, will I be able to still detect H2,N2,O2; along with CO2???

Will detection level of hydrogen changes?

Ramana

Posted: Fri Jun 29, 2007 3:09 pm
by chromatographer1
It may take a longer MS13x than a 5A to get the same separation of O2 and N2 but yes you should be able to do the same analysis.

There is usually more tailing on N2 and O2 when using a 13X rather than a 5A but it depends.

Send me you email address and I can send you chromatograms.

best wishes,

Rodney George
Senior Research and Development Scientist
Gas Separations Research
Supelco
595 North Harrison Road
Bellefonte, PA 16823

814-359-5737 voice
814-359-5459 fax
rodney.george@sial.com

Posted: Fri Jun 29, 2007 5:01 pm
by gadhamvr
Rod,
So you are pretty sure, that MS13X will still have similar characteristics, for hydrogen separation, and hence hydrogen detection, using my system.

You can mail me at gadhamvr@nmsu.edu

Regards,
Ramana

Ramana

Posted: Fri Jun 29, 2007 5:32 pm
by chromatographer1
I hope you got the chromatograms of MS5A, MS13X, and Carboxen 1000 I sent you.

best wishes,

Rod