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separation of ethylbenzene and m/p-xylene

Posted: Thu Feb 25, 2016 6:38 am
by Mungun
hi all,

How can separation of ethylbenzene and m/p-xylene be achieved?

We do use 5MS column and FID.

thank you

Re: separation of ethylbenzene and m/p-xylene

Posted: Thu Feb 25, 2016 10:47 am
by fsistere
Hi
Use a 624 column. You can separe ethylbenzene but m/p-xylene coelute. I think that to separe m and p-xylene you can use a wax column

Re: separation of ethylbenzene and m/p-xylene

Posted: Thu Feb 25, 2016 1:36 pm
by rb6banjo
Yes. You can do it on a wax phase. I do it routinely on a Zebron-Wax (60 m x 0.53 mm x 1.0 µm) column. If you're analyzing for these in carbon dioxide, you need to know that benzene and ethanol (a fairly common impurity in liquid CO2) coelute on this phase.