Chromatography Forum is a public discussion group where you can post questions, news, or messages of interest to chromatographers everywhere, but you must be registered to participate (registration is FREE). If you are a registered user, please log in.
http://www.chromforum.org/
Only in the sense that everything happens faster, so any absolute errors are smaller. Percentage errors are about the same.gradient time is more robust for steep gradient than shallow gradient, right?
Yes, but it's complicated. k* values change roughly in proportion to 1/T (in °K). Read Snyder & Dolan's book on High Performance Gradient Elution for the math (here's a link to it on Amazon: http://tinyurl.com/ct68wxz )do we have any equation to predict temperature effect on gradient retention time?