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New to analyzers
Posted: Mon Jun 17, 2013 12:34 am
by 12buckle
???
Re: New to analyzers
Posted: Mon Jun 17, 2013 1:40 am
by chromatographer1
These units monitor processes which are usually very stable and measure around a certain point. Accuracy is desired around this point so that the analyzer can track the output it is monitoring precisely, as a trend over time. It is the trend not the exact measurement that is important.
For example, an ethylene stream may be measuring acetylene content at 0-5 ppm but it may calibrate at 1 ppm and when the trend reaches 3 ppm an alarm may go off. It is not necessary that the measurement may be off by 0.1 ppm at 3 ppm, but if the calibration is at 1 ppm and the measurement hits 3 ppm (which might actually be 2.9 or 3.1 ppm) then the unit sends its alarm and it has done its job.
The plant engineer has designed these factors into the plant. To actually calibrate over a large range of a measurement, say 5% 50% and 95% is unwise, as the cost of all these calibration standards is high, they require a lot of time to monitor their consumption and use, and they may not have a long lifetime where the value they were made does not change. Buy a 95% std today and 3 months from now it may be 88%, so why bother with all the expense and trouble? It gives more opportunities for mistakes to enter into the equation. Ooops, I used the 50% calibration instead of the 95% cal std, etc.
I hope I have given you a least a glimpse into the thinking of using only one cal std on an analyzer. Of course, if several streams are being monitored with a large difference in center of their ranges, then more than one cal std might be needed.
best wishes,
Rod
Re: New to analyzers
Posted: Mon Jun 17, 2013 9:56 am
by 12buckle
Thanks a ton!
Re: New to analyzers
Posted: Mon Jun 17, 2013 10:35 am
by chromatographer1
You are welcome.
Re: New to analyzers
Posted: Mon Jun 17, 2013 12:39 pm
by rb6banjo
Rod summed it up quite well. The linear dynamic range of most detectors for gas chromatography is quite large (10^3 for something like an electron-capture detector to 10^5 or 10^6 for a flame). That's one more reason why you won't probably be too far off if you only calibrate with one point.
Re: New to analyzers
Posted: Mon Jun 17, 2013 2:19 pm
by chromatographer1
Most process analyzer chromatographs use a TCD with a thermister not a hot wire setup, believe it or not.
Second most used is the traditional FID.
Rod