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water and ecd

Posted: Sun May 05, 2013 9:25 pm
by push
Can water solution be injected gc with ecd?

Re: water and ecd

Posted: Tue May 07, 2013 2:14 am
by jss37992
The oxygen present in the H2O will max the signal of the ECD, so no it would not be a good idea to do this.

Re: water and ecd

Posted: Tue May 07, 2013 6:20 am
by dblux_
Can water solution be injected gc with ecd?
Sure :)

http://www.chromatographyonline.com/lcg ... rticle.pdf

Re: water and ecd

Posted: Wed May 08, 2013 3:12 pm
by AICMM
Push,

I wouldn't. First, why would you want to inject water unless you absolutely have to. Lots of postings on that problem throughout the forum. In this case, finding some other method would be advisable. Second, an ECD is not like an FID, you can't just flip it apart when it becomes dirty. It gets expensive when it gets dirty.

More data gets better answers.

Best regards,

AICMM

Re: water and ecd

Posted: Wed May 08, 2013 5:07 pm
by dblux_
Push,

... Second, an ECD is not like an FID, you can't just flip it apart when it becomes dirty. It gets expensive when it gets dirty.
...
Water is not dirty. It doesn't condense inside hot ECD and water vapour is much less agressive than for instance chlorinated compounds.

Re: water and ecd

Posted: Wed May 08, 2013 6:53 pm
by skunked_once
Ages ago we used to inject water into our systems to "steam clean" the ECD.