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Piperazine and N,N'-methylene bis acrylamide can be?

Posted: Fri May 20, 2005 7:27 am
by michelle.zhang
Hi, Friends,
These two samples are monomers to polymerize a copolymer. I am developing the method to test the residues.
Originally, I preferred to analyze them by GC. The bp of piperazine is 140'C only although two N in its structure. From the latter structure, I think it could be run in the GC. But I tried polar column and non-polar column (innowax 50-260'C and HP-1 50-320'C) seperatively, no any useful peaks can be used to quantify. So anyone have experience in analysis of these two samples, pls help me to clarify.
Thank you in advance.
Michelle

Posted: Fri May 20, 2005 8:18 am
by MikeD
Free piperazine certainly runs on the Varian CP-Volamine column.

thanks, and anything in details?

Posted: Fri May 20, 2005 9:31 am
by michelle.zhang
as the topic