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pi-pi interaction

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pi-pi interaction

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jiang295
I just wonder which intra molecular interaction category will pi-pi interaction be in. I think it is combination of dispersive interaction and dipole dipole interaction between aromatic compounds. So essentially, it is not just a static electronic interaction? any idea?

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Jumpshooter
pi-pi interactions occupy that 'gray area' of dipole:dipole forces of attraction where H-bonding fails to accurately (and adequately) explain the force of attraction and dispersive fails to account for transient intermolecular bonding.
Jumpshooter

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Uwe Neue
K. Croes, A. Steffens, D.H Marchand, L.R. Snyder, Relevance of π–π and dipole–dipole interactions for retention on cyano and phenyl columns in reversed-phase liquid chromatography, Journal of Chromatography A, Volume 1098, Issues 1-2, 9 December 2005, Pages 123-130

D.H. Marchand, K. Croes, J.W. Dolan, L.R. Snyder, Column selectivity in reversed-phase liquid chromatography: VII. Cyanopropyl columns, Journal of Chromatography A, Volume 1062, Issue 1, 7 January 2005, Pages 57-64

D.H. Marchand, K. Croes, J.W. Dolan, L.R. Snyder, R.A. Henry, K.M.R. Kallury, S. Waite, P.W. Carr, Column selectivity in reversed-phase liquid chromatography: VIII. Phenylalkyl and fluoro-substituted columns, Journal of Chromatography A, Volume 1062, Issue 1, 7 January 2005, Pages 65-78

avatar
jiang295
thanks a lot.

K. Croes, A. Steffens, D.H Marchand, L.R. Snyder, Relevance of π–π and dipole–dipole interactions for retention on cyano and phenyl columns in reversed-phase liquid chromatography, Journal of Chromatography A, Volume 1098, Issues 1-2, 9 December 2005, Pages 123-130

D.H. Marchand, K. Croes, J.W. Dolan, L.R. Snyder, Column selectivity in reversed-phase liquid chromatography: VII. Cyanopropyl columns, Journal of Chromatography A, Volume 1062, Issue 1, 7 January 2005, Pages 57-64

D.H. Marchand, K. Croes, J.W. Dolan, L.R. Snyder, R.A. Henry, K.M.R. Kallury, S. Waite, P.W. Carr, Column selectivity in reversed-phase liquid chromatography: VIII. Phenylalkyl and fluoro-substituted columns, Journal of Chromatography A, Volume 1062, Issue 1, 7 January 2005, Pages 65-78
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