Dibutyltin oxide ,n-butyltin trichloride,TNPP in LC MSMS ESI
Posted: Sat Nov 06, 2021 6:59 am
by Ozkan87
Hi, I want to analyze Dibutyltin oxide ,n-butyltin trichloride, Trisnonlyphenlyphosphite( TNPP) in water. We have ESI LC MSMS .Do you share with me LC method(gradient,A,B),MRMs of these molecules for LC MSMS. Thanks...
Re: Dibutyltin oxide ,n-butyltin trichloride,TNPP in LC MSMS ESI
Posted: Sun Nov 07, 2021 7:41 pm
by JMB
IN ESI +ve (like CI +ve),
[C4H9-SnCl3 + H]+ would be expected to give [C4H9-SnCl2]+ and HCl
Will [(C4H9)2Sn=O +H]+ lose OH radical OR butene OR CH3OH OR CH3CH2OH ?
I do not know.....
[TNPP + H]+ would be expected to lose C6H5OH OR Phenyl-nonyl alcohol OR both to give mixture of bis-(Phenylnonyl-O)=P+
and (Phenyl-O-)(Phenylnonyl-O-)P+
Re: Dibutyltin oxide ,n-butyltin trichloride,TNPP in LC MSMS ESI
Posted: Mon Nov 08, 2021 1:35 pm
by Ozkan87
Thanks