Hydrogen carrier on TCD detector
Posted: Tue Sep 17, 2019 5:39 pm
I'm trying to convert helium carrier to hydrogen carrier due to the explosion of helium prices. I have 2 Agilent 6890 GCs with same type column and TCD detector. I analyze hydrocarbons pesticides mostly. What I am seeing after maintenance on both to eliminate a split ratio error on either.... is that my GC on hydrogen on the TCD is less sensitive on very small peaks.
QUESTION: Is this lack of sensitivity due to using hydrogen on a TCD detector - or is one of my TCD detectors for some reason not as sensitive as the other using identical parameters? I am injecting the same test mix and I am using the best van Deemter flows for both helium and hydrogen (which yields very similar HTEP separation abilities.
QUESTION: Is this lack of sensitivity due to using hydrogen on a TCD detector - or is one of my TCD detectors for some reason not as sensitive as the other using identical parameters? I am injecting the same test mix and I am using the best van Deemter flows for both helium and hydrogen (which yields very similar HTEP separation abilities.