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Method for detecting CO
Discussions about GC and other "gas phase" separation techniques.
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I have a GC equipped with Mol Sieve 5A and a TCD and N2 as an carrier gas. I have tried different combination of oven and detector temperature but i am not able to detect CO. What conditions should i use to detect CO?
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Used to run ASTM D-1946/ EPA 3C. We used a GS-GasPro column, argon carrier gas and ran with cryo. Starting temp was -80.
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szsayyed,
A mol-sieve should separate CO - typically later in the chromatogram - unless the column has been badly abused.
The bigger question here, I think, is at what level. Using nitrogen as a carrier, the sensitivity to CO will be poor - probably low percent realistically.
If you are looking that low or lower, you should consider switching to helium or hydrogen as the carrier in order to gain sensitivity.
Likewise, keep the detector cooler if you can - on the order of 175 or so.
Best regards,
AICMM
A mol-sieve should separate CO - typically later in the chromatogram - unless the column has been badly abused.
The bigger question here, I think, is at what level. Using nitrogen as a carrier, the sensitivity to CO will be poor - probably low percent realistically.
If you are looking that low or lower, you should consider switching to helium or hydrogen as the carrier in order to gain sensitivity.
Likewise, keep the detector cooler if you can - on the order of 175 or so.
Best regards,
AICMM
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Dear sir,
I have tried injections with pure CO as well at TCD temperature 140 degrees. but even then theres no sign of a peak
Analysis is performed on the new column
I have tried injections with pure CO as well at TCD temperature 140 degrees. but even then theres no sign of a peak
Analysis is performed on the new column
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szsayyed wrote:
Dear sir,
I have tried injections with pure CO as well at TCD temperature 140 degrees. but even then theres no sign of a peak
Analysis is performed on the new column
As was mentioned above - try lower temperature. Without cryo -80 is not reachable, start at +40 in oven.
Looks like your peak is very broad and not seen as a peak.
Also very hot TCD may decrease sensitivity, try +90.
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szsayyed,
Let's start simpler. If you inject air do you get an early, good sized O2 peak?
Best regards,
AICMM
Let's start simpler. If you inject air do you get an early, good sized O2 peak?
Best regards,
AICMM
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No sir i did not get an O2 peak at the beginning
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AICMM wrote:
szsayyed,
Let's start simpler. If you inject air do you get an early, good sized O2 peak?
Best regards,
AICMM
I could observe a small peak at tha begining but not a huge one
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szayyed,
Which TCD are you using - what vendor. Some of the TCD's use range settings to moderate sensitivity so I am wondering if that might be an issue. The other think I would suggest, if possible, can you inject an aliquot of hydrogen and see what kind of response you get from that. That would certainly tell you if the TCD is dead since, against N2 carrier, it should give you a great peak.
Best regards,
AICMM
Which TCD are you using - what vendor. Some of the TCD's use range settings to moderate sensitivity so I am wondering if that might be an issue. The other think I would suggest, if possible, can you inject an aliquot of hydrogen and see what kind of response you get from that. That would certainly tell you if the TCD is dead since, against N2 carrier, it should give you a great peak.
Best regards,
AICMM
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