I always calibrated from 5ppb to 100ppb just so I would have a point at the listed detection limit. I always spiked my matrix spikes at 50ppb and never had any problems from the auditors.
If you are running only finished drinking water, you probably can get by without a guard column, we normally don't run one, but we also only get a few dozen samples per year. The big thing to remember is when you finish a run, if you are not running the next day, flush the reagent lines for several hours with DI water, then with DI water/MeOH if you are not going to run for a while to prevent bacterial growth. Every few month it is also good to flush the reagent lines with 5% Nitric acid, this will help remove any salt deposits that might clog the unit, just be sure to completely flush it out before storage or running samples, low pH kills sensitivity.
It was always strange when I first began to run the method, we never saw a positive sample, the detection limit was 5 or 6ppb yet the PT providers always sent samples that were between 500ppb and 1000ppb and the pass fail was usually 200ppb to 1000ppb for a 500ppb PT sample.
Oh and the best column we found to run them was the Hamilton PRP-X400 PEEK column. It doesn't have the limitation of the Pickering column which can not tolerate any organic at all, plus the PEEK construction won't leach any iron due to the acidic mobile phase, where iron is the main thing that will poison the stationary phase.